Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst

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成果类型：

期刊论文

作者：

Tang, Bo-Cheng;Lin, Wen-Xuan;Chen, Xiang-Long;He, Cai;Ma, Jin-Tian;...

通讯作者：

Wu, An-Xin;Lan, Yu

作者机构：

[Ma, Jin-Tian; Wu, An-Xin; Wu, Yan-Dong; Tang, Bo-Cheng; Chen, Xiang-Long; He, Cai] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.

[Lin, Wen-Xuan; Lan, Yu] Zhengzhou Univ, Coll Chem, 100 Sci Ave, Zhengzhou 450001, Henan, Peoples R China.

[Lin, Wen-Xuan; Lan, Yu] Zhengzhou Univ, Inst Green Catalysis, 100 Sci Ave, Zhengzhou 450001, Henan, Peoples R China.

[Lan, Yu] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China.

[Lan, Yu] Chongqing Univ, Chongqing Key Lab Theoret & Computat Chem, Chongqing 400030, Peoples R China.

通讯机构：

[Wu, An-Xin; Lan, Yu] C

[Lan, Yu] Z

Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.

Zhengzhou Univ, Coll Chem, 100 Sci Ave, Zhengzhou 450001, Henan, Peoples R China.

Zhengzhou Univ, Inst Green Catalysis, 100 Sci Ave, Zhengzhou 450001, Henan, Peoples R China.

语种：

英文

期刊：

Nature Communications

ISSN：

2041-1723

年：

2020

卷：

期：

页码：

5662

DOI：

10.1038/s41467-020-19508-z

基金类别：

This work was supported by the National Natural Science Foundation of China (Grants 21971080, 21971079, 21602070 and 21772051). This work was supported by ‘The Fundamental Research Funds for the Central Universities’ (CCNU15ZX002 and CCNU18QN011). This work was also supported by Henan Province Supercomputing Center.

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

Unlike the well-reported 1,2-difunctionalization of alkenes that is directed by classic pyridine and imine-containing directing groups, oxo-palladacycle intermediates featuring weak Pd-O coordination have been less demonstrated in C-H activated cascade transformations. Here we report a quadruple C-H activation cascade as well as hydro-functionalization, C-H silylation/borylation sequence based on weakly coordinated palladium catalyst. The hydroxyl group modulates the intrinsic direction of the Heck reaction, and then acts as an interrupter that...

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Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst

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