期刊论文

Chen, Jia-Rong

英文

ADVANCED SYNTHESIS & CATALYSIS

1615-4150

2018

360

18

3601-3606

10.1002/adsc.201800834

We are grateful to the NNSFC (21472058, 21472057, 21622201 and 21772053), the Science and Technology Department of Hubei Province (2016CFA050 and 2017AHB047), and the Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019) for support of this research.

本校为第一且通讯机构

The control of selectivity in the reactions of the highly reactive open-shell carbon radicals is an attractive but often challenging task. Building on the strategy of photoinduced iminyl radical-mediated C−C bond cleavage, we have developed photocatalytic neophyl rearrangement and reduction of distal carbon radicals under visible light irradiation of O-acyl oximes. This mild protocol tolerates a wide range of readily available O-acyl oximes, enabling facile synthesis of diversely substituted α,β-unsaturated nitriles and β-functionalized sat...