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Robust and Stable Acidic Overall Water Splitting on Ir Single Atoms

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成果类型:
期刊论文
作者:
Luo, Fang;Hu, Hao;Zhao, Xiao;Yang, Zehui*;Zhang, Quan;...
通讯作者:
Yang, Zehui;Cai, Weiwei;Xu, Jingxiang;Zhu, Chengzhou
作者机构:
[Yang, Zehui; Cai, Weiwei; Hu, Hao; Luo, Fang; Zhang, Quan] China Univ Geosci, Fac Mat Sci & Chem, Sustainable Energy Lab, Wuhan 430074, Peoples R China.
[Xu, Jingxiang] Shanghai Ocean Univ, Coll Engn Sci & Technol, Shanghai 201306, Peoples R China.
[Zhu, Chengzhou] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
[Yoshida, Yusuke; Zhao, Xiao; Kaneko, Takuma] Univ Electrocommun, Innovat Res Ctr Fuel Cells, Chofu, Tokyo 1828585, Japan.
通讯机构:
[Yang, ZH; Cai, WW; Zhu, Chengzhou] C
[Xu, Jingxiang] S
China Univ Geosci, Fac Mat Sci & Chem, Sustainable Energy Lab, Wuhan 430074, Peoples R China.
Shanghai Ocean Univ, Coll Engn Sci & Technol, Shanghai 201306, Peoples R China.
Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Acidic water splitting;Iridium single atom;Oxygen evolution reaction;Hydrogen evolution reaction
期刊:
NANO LETTERS
ISSN:
1530-6984
年:
2020
卷:
20
期:
3
页码:
2120-2128
基金类别:
This work is supported by the National Natural Science Foundation of China (Nos. 21703212 and 21875224) and special funding for the development of science and technology of Shanghai Ocean University (No. A2-0203-00-100231), Shanghai Pujiang Program (No. 18PJ1404200), and Nature Science Foundation of Tianjin City, China (16JCQNJC03600). F.L. also acknowledged the Fundamental Research Funds for National Universities, China University of Geosciences (Wuhan).
机构署名:
本校为通讯机构
院系归属:
化学学院
摘要:
Single-atom electrocatalysts (SAEs) can realize the target of low-cost by maximum atomic efficiency. However, they usually suffer performance decay due to high energy states, especially in a harsh acidic water splitting environment. Here, we conceive and realize a double protecting strategy that ensures robust acidic water splitting on Ir SAEs by dispersing Ir atoms in/onto Fe nanoparticles and embedding IrFe nanoparticles into nitrogen-doped carbon nanotubes ([email protected]@NCNT). When [email protected]@NCNT acts as a bifunctional electroca...

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