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Infrared diode laser spectroscopy of the He–N2O van der Waals complex in the 1285cm−1 region

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成果类型:
期刊论文
作者:
Zhu, Desheng;Wang, Ruibo;Zheng, Rui;Huang, Guangming(黄光明);Duan, Chuanxi*段传喜
通讯作者:
Duan, Chuanxi(段传喜
作者机构:
[Huang, Guangming; Duan, Chuanxi; Zheng, Rui; Zhu, Desheng; Wang, Ruibo] Huazhong Normal Univ, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
[Duan, Chuanxi] Huazhong Normal Univ, Coll Phys Sci & Technol, 152 Luoyu Rd, Wuhan 430079, Peoples R China.
通讯机构:
[Duan, Chuanxi] H
Huazhong Normal Univ, Coll Phys Sci & Technol, 152 Luoyu Rd, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Rovibrational spectrum;He-N2O;van der Waals complex;POTENTIAL-ENERGY SURFACE;QUADRUPOLE HYPERFINE-STRUCTURE;ROTATIONAL SPECTRUM;ROVIBRATIONAL SPECTRA;AR-N2O;NE-N2O;DIMER
期刊:
Journal of Molecular Spectroscopy
ISSN:
0022-2852
年:
2009
卷:
253
期:
2
页码:
88-91
基金类别:
National Natural Science Foundation of China [10604019]; Scientific Research Foundation for the Returned Overseas Chinese Scholars; State Education Ministry
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
The rovibrational spectrum of the He-N2O van der Waals complex has been recorded in the N2O-monomer nu(1) region (similar to 1285 cm(-1)) using an infrared tunable diode laser spectrometer in conjunction with a free supersonic jet expansion and an astigmatic multi-pass absorption cell. Twenty-two lines are assigned to the nu(2)-band of He-N2O. Rotational constants for the nu(2)-excited state are derived. The band-origin of the spectrum is determined to be nu(0) = 1285.0666(7) cm(-1) and shows a blue-shift of 0.1633(8) cm(-1) compared with ...

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