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Synthesis and X-ray Crystal Structure of a New Molecular Clip

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成果类型:
期刊论文
作者:
SHE NengFang(佘能芳);GAO Meng;WANG Shuai;WU AnXin
通讯作者:
Wu An-Xin
作者机构:
[SHE NengFang; GAO Meng; WU AnXin; WANG Shuai] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Wu An-Xin] C
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
molecular clip;X-ray crystal structure;boat conformation
关键词(中文):
合成;晶体结构;X射线分析;船式构象;分子削减
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2008
卷:
27
期:
7
页码:
777-780
基金类别:
The project was supported by the National Natural Science Foundation of China (20672042)
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
The synthesis and X-ray crystal structure of a new molecular clip 2 was reported. It (C24H24N4O2, M-r = 400.47) crystallizes in the space group C-2/c with a = 15.587(2), b = 8.5805(12), c = 15.259(2) angstrom, beta = 102.448(3)degrees, V = 1992.9 (5) angstrom(3), Z = 4, D-c = 1.335 g/cm(3), mu = 0.087 mm(-1) and F(000) = 848. It remains monomeric in the crystal and a tape-like structure is formed in the crystal structure of molecular clip. The most unusual structural feature of 2 is the boat conformation of i...

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