非共价拓扑异构体的研究一个基于CH…O弱氢键控制的对映选择性自组装堆积体
作者:
王治国;王宇宙;殷国栋;李义涛;佘能芳
( 佘能芳 ) ;...
作者机构:
[佘能芳; 吴安心; 王治国; 王宇宙; 殷国栋; 李义涛] 华中师范大学化学学院农药与化学生物学教育部重点实验室
会议名称:
中国化学会全国第十三届大环发化学暨第五届超分子化学学术讨论会
会议时间:
2006-08-16
会议地点:
洛阳
会议论文集名称:
中国化学会全国第十三届大环第五届超分子化学学术讨论会大环化学和超分子化学研究进展论文选集
关键词:
不对称分子夹;自组装;对映选择性堆积;二苯基甘脲;手性识别
摘要:
本文以二苯基甘脲为建筑模块合成得到一对不对称U型三维结构的拓扑异构体,该不对称分子夹在堆积过程中选择性形成一种异手性自组装二聚体AB1,这种对映选择性自组装主要是分子间CH…O和CH-π两种弱氢键协同作用的结果.其中,CH…O作用在手性识别中起着关键作用.
语种:
中文
展开
(2R,3S)-diethyl 2,3-dibenzoylsuccinate
作者:
Hu, SL;Liu, XM;Guo, HZ;Wu, AX
* ( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2006年62(5):o1966-o1967 ISSN:2053-2296
作者机构:
[Wu, AX] Cent China Normal Univ, Minist Educ, Key Lab Pesticides & Chem Biol, Coll Chem, Wuhan 430079, Peoples R China.;Hubei Normal Univ, Dept Chem & Environm Engn, Huangshi 435002, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Minist Educ, Key Lab Pesticides & Chem Biol, Coll Chem, Wuhan 430079, Peoples R China.
摘要:
In the crystal structure of the title compound, C22H 22O6, the asymmetric unit consists of one half-molecule with the other half generated by a centre of inversion. The crystal packing is stabilized by C - H⋯O intermolecular interactions. © 2006 International Union of Crystallography. All rights reserved.
语种:
英文
展开
基于二乙酯基甘脲的新型分子夹及大环化合物的合成
作者:
李义涛;郭茜旎;殷国栋;周宝晗;郭慧珍;...
作者机构:
[吴安心; 李义涛; 郭茜旎; 殷国栋; 周宝晗; 郭慧珍; 陈爱华] 华中师范大学化学学院农药与化学生物学教育部重点实验室
会议名称:
中国化学会全国第十三届大环化学暨第五届超分子化学学术讨论会
会议时间:
2006-08
会议地点:
中国河南洛阳
关键词:
二乙酯基甘脲;分子夹;大环化合物
摘要:
<正>自然界中,天然产物通常具有凹型的空腔或裂缝从而使其更好的包结客体。近年来,被合成出的具有此类空腔的主体化合物,包括分子夹、分子钳、分子碗、分子裂缝及大环化合物等, 在分子识别、分子催化、纳米材料等方面都得到了广泛的应用。设计合成具有空腔的主体化合物仍将是主一客体化学研究的热点之一。
语种:
中文
展开
Efficient C-C double-bond formation reaction via a new synthetic strategy: A self-sorting tandem reaction
作者:
Yin, Guodong;Zhou, Baohan;Meng, Xianggao;Wu, Anxin
* ( 吴安心 ) ;Pan, Yuanjiang
期刊:
Organic Letters ,2006年8(11):2245-2248 ISSN:1523-7060
作者机构:
Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.;Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China.;[Wu, Anxin] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, 152 Luoyu Rd, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, Anxin] C;Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, 152 Luoyu Rd, Wuhan 430079, Peoples R China.
摘要:
A novel and efficient carbon-carbon double-bond formation reaction via coupling of aryl or heteroaryl methyl ketones has been developed. A dimethyl sulfoxide-iodine-CuO system was proven to be efficient for this reaction and afforded the expected products in good yields. A new synthetic strategy, a self-sorting tandem reaction, was involved in this type of reaction and was presented for the first time. © 2006 American Chemical Society.
语种:
英文
展开
The absolute configuration of a nitroxide spin labeled derivative of podophyllotoxin determined by the crystal structure
作者:
Zhou, Baohan;Yin, Guodong;Meng, Xianggao;Li, Yitao;Wu, Anxin
* ( 吴安心 )
期刊:
CANADIAN JOURNAL OF CHEMISTRY ,2006年84(12):1603-1606 ISSN:0008-4042
作者机构:
[Wu, Anxin; Meng, Xianggao; Li, Yitao; Yin, Guodong; Zhou, Baohan] Cent China Normal Univ, Coll Chem, Minist Educ, Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, Anxin] C;Cent China Normal Univ, Coll Chem, Minist Educ, Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
关键词:
Crystal structure;Nitroxyl radical;Podophyllotoxin;Synthesis
摘要:
The crystal structure of the nitroxide spin labeled derivative of podophyllotoxin was first reported. X-ray analysis demonstrated that four contiguous chiral centers in the molecule, C1, C2, C3, and C4, adopt cis- (1:2), trans-(2:3), and cis- (3:4) arrangement. ©2006 NRC.
语种:
英文
展开
Substituent effects control the self-association of molecular clips in the crystalline state
作者:
Wang, Zhi-Guo;Zhou, Bao-Han;Chen, Yun-Feng;Yin, Guo-Dong;Li, Yi-Tao;...
期刊:
JOURNAL OF ORGANIC CHEMISTRY ,2006年71(12):4502-4508 ISSN:0022-3263
作者机构:
[Wu, An-Xin] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.;Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA.
通讯机构:
[Wu, An-Xin] C;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
摘要:
We report the X-ray crystal structure of 11 molecular clips and analyze the influence of substituents ( e. g., OMe, Me, and NO2) and their location on the observed crystal packing. Molecular clips 3a and 3b form tapelike structures in the crystal due to pi-pi interactions between the aromatic walls. Compounds 3d, 3eC, and 3fC form dimers driven by critical C-H center dot center dot center dot O interactions and then form tapes driven by pi-pi interactions in the crystal. These two building motifs, pi-pi and C-H center dot center dot center dot O interactions, can be used to rationalize the enantio- and diastereoselectivity observed in the X-ray crystal structures of the remaining five molecular clips. For example, the C-H center dot center dot center dot O interactions are found to dictate the formation of homochiral dimers in the structures of (+/-)-3eT and (+/-)-3fT and to control the diastereoselective formation of 6a(2)-6c(2) dimeric motifs with internal p-dimethoxy-o-xylylene walls. Overall, the results suggest that substituent effects that induce even weak intermolecular interactions ( e. g., C-H center dot center dot center dot O) can be used to reliably control crystal packing within glycoluril-based systems.
语种:
英文
展开
1,3:4,6-Bis(1,4-diphenylethynyl-2,3-xylylene)tetrahydro-3a, 6a-bis(ethoxycarbonyl)imidazo[4,5-d]-imidazole-2,5(1H,3H)-dione, a molecular clip based on di(ethoxycarbonyl)glycoluril
作者:
She, Neng‐Fang
( 佘能芳 ) ;Guo, Hui‐Zhen;Wu, An‐Xin
( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(7):o2003-o2004 ISSN:2053-2296
通讯作者:
Wu, AX
作者机构:
[She, Neng‐Fang; Wu, An‐Xin; Guo, Hui‐Zhen] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.
摘要:
The molecule of the title compound, C58H42N 4O6, a molecular clip based on the glycoluril framework, occupies a special position on a twofold axis passing through the mid-point of the gycoluril C-C bond. The planes of the central benzene rings in the opposite wings of the molecular clip form a dihedral angle of 41.6 (4)°. No dimers typical for molecular clip packings are observed in the crystal structure of the title compound. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
rac-Diethyl 2,3-bis(2-methoxybenzoyl)succinate
作者:
Meng, Xiang‐Gao;Wu, An‐Xin
( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(10):o3203-o3204 ISSN:2053-2296
通讯作者:
Meng, XG
作者机构:
[Wu, An‐Xin; Meng, Xiang‐Gao] Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Meng, XG] C;Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China.
摘要:
In the rac isomer mixture of the title compound, C24H 26O8, the molecules are weakly linked via C-H⋯O and π-π interactions, forming a three-dimensional network. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
Diethyl 2-(1,3-benzodioxol-5-yl)-5-(3,4-dimethoxy-phenyl)furan-3,4- dicarboxylate
作者:
Hu, SL;Wang, ZG;Wu, AX
* ( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(9):o2801-o2803 ISSN:2053-2296
作者机构:
[Wu, AX] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticides & Chem Biol, Wuhan 430079, Peoples R China.;Hubei Normal Univ, Dept Environm Chem & Engn, Huangshi 435002, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticides & Chem Biol, Wuhan 430079, Peoples R China.
摘要:
In the title compound, C25H24O9, the substituted benzene rings are twisted away from the furan ring. The dihedral angle between the two benzene rings is 52.1 (1)°. In the crystal structure, the molecules exist as hydrogen-bonded dimers, the molecules being connected through very weak C-H⋯O hydrogen bonds. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
2,2,6,6-Tetramethylpiperidin-4-ol
作者:
She, NF
( 佘能芳 ) ;Guo, HZ;Yin, GD;Wu, AX
* ( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(9):o2902-o2903 ISSN:2053-2296
作者机构:
[She, NF; Wu, AX; Guo, HZ; Yin, GD] Cent China Normal Univ, Coll Chem, Key Lab Pesticides & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Coll Chem, Key Lab Pesticides & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
摘要:
The molecule of the title compound, C9H19NO, lies on a mirror plane. Intermolecular N - H⋯O and O - H⋯N hydrogen bonds are observed in the crystal structure. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
Diethyl 4,8-dioxo-2,6-di-p-chlorophenyl-1,3,5,7-tetrahydro-2,3a,4a,6,7a,8a- hexaazacyclopenta-[def]fluorene-8b,8c-dicarboxylate
作者:
Yin, GD;Zhou, BH;Wu, AX
* ( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(9):o2787-o2788 ISSN:2053-2296
作者机构:
[Wu, AX; Yin, GD; Zhou, BH] Cent China Normal Univ, Coll Chem, Key Lab Pesticide Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Coll Chem, Key Lab Pesticide Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
摘要:
In the title compound, C28H32Cl2N 6O6, the dihedral angle between the two adjacent five-membered rings in the glycoluril unit is 70.18 (9)° and molecules are connected mainly by G-H⋯O intermolecular interactions. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
2,6-Dibenzyl-8b,8c-diphenyl-2,3a,4a,6,7a,8a-hexaazaperhydrocyclopenta[def] fluorene-4,8-dione
作者:
Li, Yi‐Tao;Long, Tao;Wu, An‐Xin
( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(8):o2374-o2375 ISSN:2053-2296
通讯作者:
Wu, AX
作者机构:
[Wu, An‐Xin; Li, Yi‐Tao; Long, Tao] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
摘要:
The molecule of the title compound, C34H32N 6O2, exhibits normal geometric parameters. The two terminal phenyl rings make a dihedral angle of 69.24 (2)° with each other. The crystal packing is stabilized mainly by van der Waals interactions. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
Tetraethyl 2,2′-(p-phenylenedimethylene)dimalonate
作者:
Chen, AH;Wang, ZG;Yin, GD;Wu, AX
* ( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(10):o3240-o3241 ISSN:2053-2296
作者机构:
[Wu, AX; Wang, ZG; Yin, GD; Chen, AH] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticides & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticides & Chem Biol, Wuhan 430079, Peoples R China.
摘要:
The molecule of the title compound, C22H30O8, contains a crystallographic inversion centre located at the middle of the benzene ring.
语种:
英文
展开
1,2-Dimethyl-4,5-bis(phenylethynyl)benzene
作者:
She, Nengfang
( 佘能芳 ) ;Guo, Huizhen;Li, Yitao;Wu, Anxin
( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(6):o1790-o1792 ISSN:2053-2296
通讯作者:
Wu, AX
作者机构:
[She, Nengfang; Wu, Anxin; Li, Yitao; Guo, Huizhen] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.
摘要:
The title compound, C24H18, possesses a twofold rotation axis, which bisects the 1,2-dimethylbenzene ring. In the crystal structure, all three benzene rings are essentially coplanar, the angle between the central and terminal rings being 3.8 (1)°. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
Ethyl 3-oxo-3-(3,4,5-trimethoxyphenyl)propanoate
作者:
Meng, Xiang‐Gao;Wu, An‐Xin
( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(11):o3611-o3612 ISSN:2053-2296
通讯作者:
Meng, XG
作者机构:
[Wu, An‐Xin; Meng, Xiang‐Gao] Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Meng, XG] C;Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China.
摘要:
The molecules of the title compound, C14H18O 6, are linked into a three-dimensional network by a combination of C H⋯O hydrogen bonds and C-H⋯ π and π-π interacions © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
Diethyl cis-1,2,3,4,5,10-hexahydro-7,8-dimethyl-1,4-dioxo-2,3,4a,10a-tetraazabenzo[g] cyclopent-[cd]azulene-2a,10b-dicarboxylate chloroform disolvate
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(5):o1453-o1455 ISSN:2053-2296
作者机构:
[Wu, AX; Wei, FQ] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
摘要:
The crystal structure of the title compound, 4,5-dimethyl-1,2-xylylene-derived diethoxycarbonyl glycoluril, C 20H24N4O6·2CHCl3, is reported. In the crystal structure, there are not only intermolecular hydrogen bonds, but also π-π stacking interactions. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
5-Butyl-6-methyl-2-thioxo-2,3-dihydro-pyrimidin-4(1 H)-one
作者:
Long, T;Zhou, HB;Wu, AX
* ( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(7):o2169-o2171 ISSN:2053-2296
作者机构:
[Wu, AX; Zhou, HB; Long, T] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
摘要:
In the title compound, C9H14N2OS, the butyl group is disordered over two orientations. In the crystal structure, the inversion-related molecules are linked by N-H⋯O [N⋯O = 2.823 (3) Å] and N-H⋯S [N⋯S = 3.346 (2) Å] hydrogen bonds to form chains along [210]. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
Ethyl 2,5-diphenylfuran-3-carboxylate
作者:
Meng, XG;Wu, AX
* ( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(9):o2808-o2809 ISSN:2053-2296
作者机构:
[Wu, AX; Meng, XG] Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China.
摘要:
In the title compound, C19H16O3, the dihedral between the two phenyl rings is 12.6 (1)°. An intramolecular hydrogen bond and weak C-H⋯π interactions are observed. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
N,N′-Bis(N,N-dimethyl-p-toluidine)bis(ethoxy-carbonyl)glycoluril
作者:
Yin, Guo‐Dong;Zhou, Bao‐Han;Chen, Yun‐Feng;Wu, An‐Xin
( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(8):o2632-o2634 ISSN:2053-2296
通讯作者:
Wu, AX
作者机构:
[Wu, An‐Xin; Yin, Guo‐Dong; Chen, Yun‐Feng; Zhou, Bao‐Han] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.
摘要:
In the title compound (systematic name: diethyl 4,8-dioxo-2,6-di-p-tolyl-1, 3,5,7-tetrahydro-2,3a,4a,6,7a,8a-hexaazacyclopenta[def]fluorene-8b, 8c-dicarboxylate), C28H32N6O6, the dihedral angles between the two fused five-membered rings in the glycoluril unit and between the two terminal benzene rings are 71.8 (2) and 88.5 (1)°, respectively. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开
5-Benzyl-6-methyl-2-thioxo-2,3-dihydro-pyrimidin-4(1H)-one
作者:
Hu, SL;Yin, GD;Wu, AX
* ( 吴安心 )
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY ,2005年61(8):o2408-o2409 ISSN:2053-2296
作者机构:
[Wu, AX] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.;Hubei Normal Univ, Dept Chem & Environm Engn, Huangshi 435002, Peoples R China.
通讯机构:
[Wu, AX] C;Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
摘要:
In the title compound, C12H12N2OS, the dihedral angle between the benzene and pyrimidine rings is 84.1 (1)°. The molecules are linked by centrosymmetric pairs of N-H⋯O [N⋯O = 2.817 (2) Å] and N-H⋯S [N⋯S = 3.357 (2) Å] hydrogen bonds to form chains. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
语种:
英文
展开