摘要:
Methyl 1-(5-methyl isoxazol-3-oxy acetoxy) alkyl methyl phosphinates were synthesized by the condensation of O-methyl methyl 1-hydroxyalkyl phosphinates moiety with 5-methyl isoxazol-3-oxy acetyl chloride and were tested for plant growth regulatory activity and herbicidal activity. Some compounds exhibited notable plant regulatory activity and herbicidal activity.
作者:
Zhang, AD(张爱东);Jaffrezic-Renault, N*;Wan, HL;Hou, YX;Chovelon, JM
期刊:
Materials Science and Engineering C: Materials for Biological Applications,2002年21(1-2):91-96 ISSN:0928-4931
通讯作者:
Jaffrezic-Renault, N
作者机构:
Ecole Cent Lyon, IFoS, UMR 5621, CNRS, F-69131 Ecully, France.;Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China.;Univ Lyon 1, LACE, UMR 5634, CNRS, F-69622 Villeurbanne, France.;[Jaffrezic-Renault, N] Ecole Cent Lyon, IFoS, UMR 5621, CNRS, 36 Ave Guy Collongue,BP 163, F-69131 Ecully, France.
通讯机构:
[Jaffrezic-Renault, N] E;Ecole Cent Lyon, IFoS, UMR 5621, CNRS, 36 Ave Guy Collongue,BP 163, F-69131 Ecully, France.
会议名称:
3rd Maghreb/Europe Meeting on Materials and Their Applications for Devices and Physical, Chemical and Biological Sensors
会议时间:
OCT 29-30, 2001
会议地点:
HAMMAMET, TUNISIA
会议主办单位:
Ecole Cent Lyon, IFoS, UMR 5621, CNRS, F-69131 Ecully, France.^Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China.^Univ Lyon 1, LACE, UMR 5634, CNRS, F-69622 Villeurbanne, France.
摘要:
A number of 1-alkyl-1,3,2-diazaphospholidin-4-thione-2-sulfides(2) have been synthesized by the cyclization reaction of Lawesson's reagent with 3- alkyl- glycinamides(1). The bio-assay indicates that some of compounds prepared have good selective herbicidal activity and the quantitative structure- herbicidal activity relationship (QSAR) of compounds(2) has also been studied.
期刊:
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,1999年144(1):633-636 ISSN:1042-6507
通讯作者:
He, HW
作者机构:
[He, HW; Hu, LM; Liu, XF; Wang, SQ; Liu, ZJ] Cent China Normal Univ, Inst Organ Synth, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[He, HW] C;Cent China Normal Univ, Inst Organ Synth, Wuhan 430079, Hubei, Peoples R China.
会议名称:
XIVth International Conference on Phosphorus Chemistry (XIVth-ICPC)
会议时间:
JUL 12-17, 1998
会议地点:
CINCINNATI, OH
会议主办单位:
Cent China Normal Univ, Inst Organ Synth, Wuhan 430079, Hubei, Peoples R China.
关键词:
Condensation;Dealkylation of phosphorates;Phosphonic acid;Trimethylsilyl chloride/sodium iodide
摘要:
Using the silylation procedure with chlorotrimethylsilane/sodium iodide followed by alcoholysis, 1-(dichlorophenoxy acetoxy)alkyl phosphonic acid dimethyl esters can be transformed into the parent phosphonic acids without influence on carboxylate ester group.
期刊:
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,1999年144(1):655-658 ISSN:1042-6507
通讯作者:
Zhan, CG
作者机构:
[Zhan, CG] Cent China Normal Univ, Dept Chem, Wuhan 430070, Peoples R China.;[Zhan, CG] Univ Notre Dame, Radiat Lab, No
通讯机构:
[Zhan, CG] C;Cent China Normal Univ, Dept Chem, Wuhan 430070, Peoples R China.
会议名称:
XIVth International Conference on Phosphorus Chemistry (XIVth-ICPC)
会议时间:
JUL 12-17, 1998
会议地点:
CINCINNATI, OH
会议主办单位:
Cent China Normal Univ, Dept Chem, Wuhan 430070, Peoples R China.^Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA.
关键词:
P-31 NMR chemical shift;phosphorylated amino acid;reaction mechanism
摘要:
Based on a detailed ab initio study on the reaction mechanism of phosphoryl ester exchange and N --> O migration reactions of dimethyloxyphosphoryl-threonine, ab initio GIAO magnetic shielding calculations have been carried out on the predicted stable intermediate and the corresponding reactant and product. The P-31 NNR chemical shift of the most stable penta-coordinate phosphorus intermediate has been predicted as about -71 ppm. The theoretical results may lead to a possible way to experimentally examine our predictions and to monitor the most stable intermediate during the reaction process.
作者机构:
[Guanghan L.; Dandan, S; Hong, J] Department of Chemistry, Central China Normal University, 430070, Wuhan, China
通讯机构:
[Lu, GH] C;CENT CHINA NORMAL UNIV,DEPT CHEM,WUHAN 430070,PEOPLES R CHINA.
会议名称:
Workshop on Mediterranean Aspects of Meat Quality as Related to Muscle Biochemistry
会议时间:
MAY 09-10, 1996
会议地点:
SEGOVIA, SPAIN
摘要:
A sensitive anodic stripping procedure for trace nitrite in the presence of added cetyltrimethylammonium bromide (CTMAB) is described. The method is based on the electrodeposition and subsequent oxidation of CTMAB-nitrite complex on a glassy carbon electrode in a supporting solution, consisting of Britten-Robinson buffer solution, pH range 3.6-4.0, and CTMAB. The peak height is proportional to the concentration of nitrite over the range 0.01-0.25 μg ml-1, and the relative standard deviation is less than 3.3%. This method has been used for the determination of trace nitrite in water and meat products with 90-110% recovery.
会议主办单位:
CENT CHINA NORMAL UNIV,DEPT CHEM,WUHAN 430072,PEOPLES R CHINA.
关键词:
Aerobacter aerogenes;kinetics;microcalorimetry;multiplication rate constant;Schiff base
摘要:
Microcalorimetry was used to study the kinetics of action of five kinds of Schiff base on a strain of Aerobacter aerogenes. Differences in their capacities to suppress the metabolism of this bacterium were observed. The extent and duration of the inhibitory effect on the metabolism as judged from the multiplication rate constant, k, varied with the different Schiff bases. The multiplication rate constants, k, of Aerobacter aerogenes (in log phase) in the presence of Co(III)-NG and Ni-NG (NG: D-glucosamine-beta-naphthol aldehyde) decreased with the increasing concentrations of the compounds C, but the relationship between k and C was not of good linearity. For Fe(III)-NG, the multiplication rate constants are constant irrespective of variations in concentration. Similarly over the concentration range 50-200 mu g mL(-1,) there is nearly change in the inhibitory effects of NG on Aerobacter aerogenes, while they are slightly reduced beyond 200 mu g mL(-1). The experimental results revealed that the sequence of antibiotic activity of Schiff base drugs is: Co(III)-NG > Ni-NG > NG > Fe(III)-NG.