作者：
Zhang, Fan*;Sun, Yue;Tian, Demei;Shin, Weon Sup*;Kim, Jong Seung;...
期刊：
Chemical Communications,2016年52(86):12685-12693 ISSN：1359-7345
通讯作者：
Zhang, Fan;Shin, Weon Sup
作者机构：
[Zhang, Fan; Sun, Yue; Tian, Demei; Li, Haibing] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol CCNU, Wuhan 430079, Peoples R China.;[Shin, Weon Sup; Kim, Jong Seung] Korea Univ, Dept Chem, Seoul 136701, South Korea.
通讯机构：
[Shin, Weon Sup] D;[Zhang, Fan] K;Department of Chemistry, Korea University, Seoul 136-701, Korea<&wdkj&>Key Laboratory of Pesticide and Chemical Biology (CCNU), Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China
摘要：
Host-guest recognition plays an important role in biological analysis and biosensing. Accordingly, great efforts have been devoted to the development of sensors using versatile 3D surface materials. These functionalized nanomaterials possess the advantages of high selectivity and visual signals, enabling the selective detection of ions, amino acids, proteins, and other biological molecules. Therefore, in this feature article, we present some significant and representative examples of molecular recognition on calixarene functionalized 3D surface nanomaterials. By virtue of host-guest interactions, the functional interfaces displaying high selectivity and featuring a reversible switch response towards the environmental stimuli with various signal output (electrochemical and optical signals) are herein introduced. Furthermore, various 3D surface materials with unique signal amplification in molecular recognition are presented, including quantum dots (QDs), metal nanoparticles (NPs), nanotubes, and mesoporous silica. These excellent properties enable calixarene-functionalized 3D materials to become an outstanding platform for molecular recognition, offering convenient approaches for sensing and separation.
作者机构：
[Zeng, Xiangfei; Li, Haibing; Bi, Jiahai; Tian, Demei] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol CCNU, Wuhan 430079, Peoples R China.
通讯机构：
[Li, Haibing] C;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol CCNU, Wuhan 430079, Peoples R China.
摘要：
A monofunctionalized anthracene pillar[5]arene (MAP5) was designed and synthesized by a click reaction. MAP5 was bound to an ionic liquid through host–guest interactions to modify a gold interface. The bonding and release of MAP5 was readily and reversibly controlled by temperature regulation. The developed temperature-responsive switch at an interface can be used in memory storage, drug delivery, and sensing.
作者：
Xuan Xiao;De-mei Tian;Hong-tao Deng;Hai-bing Li
作者机构：
[Xuan Xiao; De-mei Tian; Hong-tao Deng; Hai-bing Li] Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University
会议名称：
中国化学会第九届全国有机化学学术会议
会议时间：
2015-07-28
会议地点：
中国吉林长春
摘要：
<正>For biological material,the study of protein adsorption on the surface is an important content,only have a protein adsorption is not a good biological materials,it still remains to build a reversib
通讯机构：
[Tian, Demei] C;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol CCNU, Wuhan 430079, Peoples R China.
摘要：
A new naphthol-appended calix[4]arene (NOC4) has been synthesized and characterized. NOC4 is clicked onto a microstructured Au surface and exhibits selective macroscopic recognition of metolcarb (MC) via contact angle measurements. The proposed wettability sensing device displays remarkable specificity and is fast and easy to use, which should be suitable for the rapid detection of MC in environmental monitoring.
摘要：
A novel coumarin-pillar[5]arene derivative (P5C10) was prepared. Fluorescence spectroscopy indicates that P5C10 shows good selectivity towards methyl-parathion. A combination of NMR spectra, MALDI-TOF spectra and computational calculations reveals the formation of a host-guest complex driven by π-π stacking interactions.
作者机构：
[Yue Sun; Demei Tian; Haibing Li] Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University
会议名称：
中国化学会第九届全国有机化学学术会议
会议时间：
2015-01-01
会议地点：
中国吉林长春
会议论文集名称：
中国化学会第九届全国有机化学学术会议论文摘要集(8)
摘要：
<正>Enantiomer discrimination monosaccharides from water is a difficult task due to their low affinity for substrates and subtle variations in the sugar structures they are hydro-mimetic,yet this discrimination is critical for human immunity and glycolbiology.Toward the realization of
摘要：
In recent years, calixarene-based fluorescent chemosensors for mercury(II) are mushroom growth because of its intrinsic sensitivity. The design of the highly selective calixarene-based chemosensors towards mercury(II) is still a challenging task. In this paper, the progress of highly selective fluorescent sensor for mercury(II) based on calixarene derivatives is reviewed according to a mono-fluorophore chemosensor and a bi-fluorophore chemosensor. Some new developments such as calixarene-modified nanoparticles are also covered.
作者机构：
[Xiangfei Zeng; Demei Tian; Haibing Li] Key Laboratory of Pesticide and Chemical Biology (CCNU), Ministry of Education, College of Chemistry, Central China Normal University
会议名称：
中国化学会第九届全国有机化学学术会议
会议时间：
2015-07-28
会议地点：
中国吉林长春
摘要：
<正>Gene therapy with broad-spectrum,safe,specific and effective advantage compared to traditional chemical treatment.~1 In recent years,through improvement of drug delivery systems thus enhancing the
作者机构：
[Fan Zhang; Junkai Ma; Demei Tian; Haibing Li] Key Laboratory of Pesticide and Chemical Biology (CCNU), Ministry of Education, College of Chemistry, Central China Normal University
会议名称：
中国化学会第九届全国有机化学学术会议
会议时间：
2015-07-28
会议地点：
中国吉林长春
摘要：
<正>It is of great significant to investigate the process of mercury ions enter the organism and result in toxic.[1]Given these points,we try to obtain the mercury（II）ion-gate by the introduction of molecular switch.Pillar[5]arene as a new type of macrocyclic molecular has been intensively
通讯机构：
[Li, Haibing] C;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol CCNU, Wuhan 430079, Peoples R China.
摘要：
Ion-controlled switchable progress is very important in many biological behaviors. Here, we reported K(+)-controlled switch, this switch system exhibited excellent carbaryl (G) binding/release by fluorescent (FL), ultraviolet-visible (UV) spectrums and (1)H NMR spectroscopy. More importantly, the K(+)-controlled G binding/release switch based on C4C5 not only in the solution, but also on the surface, promising for the application for the pesticide controlled release.
作者机构：
[Ren Hu; Demei Tian; Haibing Li] Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University
会议名称：
中国化学会第九届全国有机化学学术会议
会议时间：
2015-07-28
会议地点：
中国吉林长春
摘要：
The living organisms respond differently to the enantiomers of various drugs. Irinotecan is an important candidate in the searching of anticancer drugs.~1 It is reported that the configuration of the
