作者：
Yang, Xiao Fei;Zhang, Ming-Xing;Fu, De Bin;Wang, Yang;Yin, Jun;...
期刊：
CHEMISTRY-A EUROPEAN JOURNAL,2022年28(72) ISSN：0947-6539
通讯作者：
Hua Liu, Sheng(chshliu@mail.ccnu.edu.cn)
作者机构：
[Yang, Xiao Fei; Wang, Yang; Liu, Sheng Hua; Fu, De Bin; Yin, Jun; Zhang, Ming-Xing] Cent China Normal Univ, Minist Educ, Coll Chem, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.;[Zhang, Ming-Xing] Hubei Univ Educ, Coll Chem & Life Sci, Hubei Key Lab Purificat & Applicat Plant Anticanc, Wuhan 430205, Peoples R China.
通讯机构：
[Prof. Sheng Hua Liu] K;Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 430079 Wuhan, P. R. China
关键词：
aggregation-induced emission;near-infrared luminescence;osmium complexes;pentacyclic and hexacyclic osmaarynes;photothermal conversion
摘要：
As a colorless, highly toxic and widely used chemical reagent, phosgene poses a potentially serious threat to public health and environmental safety. Therefore, there is an urgent need to develop a simple and sen-sitive method for detecting phosgene. In this work, a ratiometric fluorescent probe (NED) for phosgene was developed by utilizing 4-substituted 1,8-naphthimide unit as the fluorophore and ethylenediamine as the recognition moiety. The probe NED undergoes intramolecular cyclization reaction with phosgene, resulting in a remarkable ratiometric fluorescence response. The probe NED displays high sensitivity (LOD = 4.9 nM), excellent ratiometric fluorescence signal, and high selectivity toward phosgene over other relevant analytes. In addition, paper test strip capable of visually detecting gaseous phosgene has also been fabricated. (c) 2021 Elsevier B.V. All rights reserved.
作者机构：
[Chen, Weijie; Chen, Huijuan; Huang, Yurou; Yin, Jun] Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan;430079, China;[Tan, Ying; Tan, Chunyan] State Key Laboratory of Chemical Oncogenomics, Key Laboratory of Chemical Biology, Shenzhen International Graduate School, Tsinghua University, Guangdong, Shenzhen;518055, China;[Xie, Yuan] Guangdong Provincial Key Laboratory of Radioactive and Rare Resource Utilization, Shaoguan
通讯机构：
[Ying Tan; Chunyan Tan] S;[Jun Yin] K;Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China<&wdkj&>State Key Laboratory of Chemical Oncogenomics, Key Laboratory of Chemical Biology, Shenzhen International Graduate School, Tsinghua University, Shenzhen, Guangdong 518055, P. R. China
作者机构：
[管怡晗; 尹军; Liu S.; 刘盛华] Central China Normal University, College of Chemistry, Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Wuhan, 430000, China
通讯机构：
[Yin, J.] C;Central China Normal University, China
作者机构：
[Zhang, Jing; Liu, Sheng Hua; Wang, Xiao-Yan; Yin, Jun] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.;[Zhang, Jing; Tang, Ben Zhong] Hong Kong Univ Sci & Technol, Chinese Natl Engn Res Ctr Tissue Restorat & Recon, Dept Chem & Biol Engn, Inst Adv Study,Dept Chem,Kowloon, Clear Water Bay, Hong Kong, Peoples R China.;[Zhang, Jing; Tang, Ben Zhong] Hong Kong Univ Sci & Technol, Inst Mol Funct Mat, Kowloon, Clear Water Bay, Hong Kong, Peoples R China.
通讯机构：
[Liu, Sheng Hua] C;[Tang, Ben Zhong] H;Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.;Hong Kong Univ Sci & Technol, Chinese Natl Engn Res Ctr Tissue Restorat & Recon, Dept Chem & Biol Engn, Inst Adv Study,Dept Chem,Kowloon, Clear Water Bay, Hong Kong, Peoples R China.;Hong Kong Univ Sci & Technol, Inst Mol Funct Mat, Kowloon, Clear Water Bay, Hong Kong, Peoples R China.
摘要：
The influence of the aggregation-induced emission (AIE) effect on the luminescence and the chirality of two chiral Au clusters (R)-1 and (S)-1 was well demonstrated. Their solid states exhibited extremely bright phosphorescence with quantum yields above 70%. The two clusters were free of luminescence and chirality in diluted solution. Meanwhile, the formation of aggregate states could not only induce both the luminescence and the chirality, but also further facilitate their enhancements, which resulted in the output and the modulation of desirable circularly polarized luminescence.
作者机构：
[Liu, Sheng Hua; Yang, Xiaofei; Yin, Jun; Zhang, Ming-Xing] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.;[Lin, Lu; Zhu, Jun] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China.;[Lin, Lu; Zhu, Jun] Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat iChEM, Fujian Prov Key Lab Theoret & Computat Chem, Xiamen 361005, Peoples R China.;[Lin, Lu; Zhu, Jun] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China.;[Zhang, Ming-Xing] Hubei Univ Educ, Hubei Key Lab Purificat & Applicat Plant Anticanc, Coll Chem & Life Sci, Wuhan 430205, Peoples R China.
通讯机构：
[Prof. Jun Zhu] S;[Prof. Sheng Hua Liu] K;Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 430079 Wuhan, P. R. China<&wdkj&>State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou, P. R. China<&wdkj&>State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, P. R. China
作者机构：
[Yoon, Juyoung; Ko, Gyeongju; Kwon, Nahyun; Ha, Jeongsun; Lee, Dayoung] Ewha Womans Univ, Dept Chem & Nanosci, Seoul 03760, South Korea.;[Kim, Hwan Myung; Lim, Chang Su] Ajou Univ, Dept Energy Syst Res, Suwon 443749, South Korea.;[Yin, Jun] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.;[Yin, Jun] Cent China Normal Univ, Hubei Int Sci & Technol Cooperat Base Pesticide &, Wuhan 430079, Peoples R China.;[Yin, Jun] Cent China Normal Univ, Int Joint Res Ctr Intelligent Biosensing Technol, Wuhan 430079, Peoples R China.
通讯机构：
[Jun Yin] K;[Hwan Myung Kim; Juyoung Yoon] D;Department of Energy Systems Research, Ajou University, Suwon 443-749, Korea<&wdkj&>Key Laboratory of Pesticide and Chemical Biology, Ministry of Education;Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis;International Joint Research Center for Intelligent Biosensing Technology and Health
作者机构：
[Yang, Guang-Fu; Liu, Shi-Yu; Yang, Wen-Chao; Yin, Jun; Guo, Wu-Yingzheng; Mei, Long-Can; Fu, Yi-Xuan; Sun, Yao] Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensor Technol &, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
通讯机构：
[Wen-Chao Yang; Guang-Fu Yang] K;Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, International Joint Research Center for Intelligent Biosensor Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China
作者机构：
[Liu, Sheng Hua; Yin, Jun; He, Yongxin] Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensing Technol, Key Lab Pesticide & Chem Biol,Minist Educ,Hubei I, Wuhan 430079, Peoples R China.;[Yoon, Juyoung] Ewha Womans Univ, Dept Chem & Nanosci, Seoul 120750, South Korea.
通讯机构：
[Yin, Jun] C;[Yoon, Juyoung] E;Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensing Technol, Key Lab Pesticide & Chem Biol,Minist Educ,Hubei I, Wuhan 430079, Peoples R China.;Ewha Womans Univ, Dept Chem & Nanosci, Seoul 120750, South Korea.
摘要：
Reactive oxygen species (ROS) are a type of active species in body, and can participate in the process of tumor development under the condition of oxidative stress, which can lead to the apoptosis of cancer cells through a variety of different mechanisms. Photodynamic therapy (PDT) is a novel method of treating tumor with photosensitive drugs and laser activation. However, PDT suffers from the poor penetrating depth of tissue of excitation light. By comparison, sonodynamic therapy (SDT) adopts high-penetrating sound waves to trigger the ultrasound-responsive materials called sonosensitizers for the treatment of cancer by different mechanisms such as ROS, ultrasound response cavitation, and thermal effects. The efficiency of SDT is bound up with molecular structures and performances of sonosensitizers, which has promoted the design of sonosensitive agents and their development in various biological fields. In clinical treatment, regulating the tumor microenvironment offers a door and new ideas for effective tumor treatment. For tumor microenvironment (TME) involving pH values, excessive production of hydrogen peroxide, scientists have designed and synthesized many nanomaterials to produce hydroxyl radicals (center dot OH) for tumor chemodynamic therapy (CDT) through Fenton and Fenton-like reactions. Many studies have indicated that its therapeutic efficiency is associated with the increase of center dot OH production in situ of the tumor. Many approaches based on Fenton reaction have been used to improve the production of center dot OH, including the choice of nanomaterials and the adjustment of the microenvironment. In view of the above two new treatment methods, this article summarizes, discusses and enlightens the SDT-related sonosensitizers and CDT-related nanomaterials in recent years, and discusses their applications and potential challenges. (C) 2020 Elsevier B.V. All rights reserved.
期刊：
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,2021年69(46):13700-13712 ISSN：0021-8561
通讯作者：
Jun Yin
作者机构：
[Zeng, Xiaoyan; Chen, Weijie; Liu, Chunrong; Yin, Jun; Yang, Guang-Fu] Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan, Hubei 430079, People’s Republic of China
通讯机构：
[Jun Yin] K;Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan, Hubei 430079, People’s Republic of China
关键词：
agricultural chemistry;detection in plants;fluorescent probes;in vivo bioimaging;reactive sulfur species
摘要：
Sulfur is an element that is indispensable throughout the growth of plants. In plant cells, reactive sulfur species (RSS) play a vital role in maintaining cellular redox homeostasis and signal transduction. There is demand accordingly for a simple, highly selective, and sensitive method of RSS detection and imaging for monitoring dynamic changes and clarifying the biological functions of RSS in plant systems. Fluorescent analysis based on organic small-molecule fluorescent probes is an effective and specific approach to tracking plant RSS characteristics. This perspective summarizes the recent progress regarding organic small-molecule fluorescent probes for RSS monitoring, including small-molecule biological thiols, hydrogen sulfide, and sulfane sulfurs, in plants; it also discusses their response mechanism toward RSS and their imaging applications in plants across the agricultural chemistry field.
期刊：
Methods in Enzymology,2021年657:223-247 ISSN：0076-6879
通讯作者：
Yin, Jun;Yang, Guang-Fu
作者机构：
[Yang, Guang-Fu; Yin, Jun; Yang, GF; Chen, Weijie; Ye, Fengying] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ,Int Joint Res Ctr Intelligent Biosens, Wuhan, Peoples R China.
通讯机构：
[Yin, J; Yang, GF] C;Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ,Int Joint Res Ctr Intelligent Biosens, Wuhan, Peoples R China.
摘要：
Benzobisthiadiazole as a typical electron acceptor, has been widely used to design fluorescent dyes and photoacoustic (PA) agents. With the strategy of constructing donor-acceptor-donor (D-A-D) type of electron characteristics, benzobisthiadiazole derivatives tend to behave stable in near-infrared absorption and emission, which is beneficial to PA imaging. In this chapter, two molecular design strategies are combined to improve the photoacoustic imaging effects of new PA contrast agent IR-1302 NPs, by installing strengthened conjugated bridges and electron donors. The nanoparticles exhibit high-contrast noninvasive photoacoustic imaging in tumor models with longer wavelength absorption and emission and show potential as a clinic contrast agent.
作者机构：
[Huang, Yurou; Chen, Weijie; Yin, Jun] Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensing Technol, Key Lab Pesticide & Chemical Biol,Minist Educ, Wuhan 430079, Peoples R China.;[Huang, Yurou; Chen, Weijie; Yin, Jun] Hubei Univ, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China.;[Yoon, Juyoung; Chung, Jeewon] Ewha Womans Univ, Dept Chem & Nano Sci, 11-1 Daehyon Dong, Seoul 120750, South Korea.
通讯机构：
[Jun Yin] K;[Juyoung Yoon] D;Key Laboratory of Pesticide and Chemical Biology, Ministry of education, Hubei International Scientific and technological cooperation Base of Pesticide and Green Synthesis, International Joint research center for Intelligent Biosensing Technology and Health, College of chemistry, Central China Normal University, Wuhan 430079, P. R. China<&wdkj&>Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan 430062, P. R. China<&wdkj&>Department of Chemistry and Nano Science, Ewha Womans University, 11-1 Daehyon-Dong, Sodaemun-Ku, Seoul 120-750, Korea
摘要：
Mercury ions are highly toxic and can accumulate along food chains in water, soil, crops and animals. Effective detection of mercury ions in various media is of great significance for maintaining the ecological environment and protecting people’s health. In this work, a mercury ions specific fluorescent probe was developed by a simple one-step reaction of commercial substrates of 4-chloro-7-nitro-2,1,3-benzoxadiazole and 1-(2-aminoethyl)-4-methylpiperazine. Investigation on sensing behavior showed that this probe had high sensitivity and selectivity towards mercury ions. Furthermore, this probe could be used as a tool to track the level of mercury ions in living system. In living cells, the probe with green emission emitted a bright red fluorescence when it was bound to mercury ions. In Arabidopsis thaliana, similar red emission could be detected from the root tip and stalk when A. thaliana was grown in culture medium containing mercury ions. The imaging in zebrafish showed that mercury ions were mainly concentrated in the stomach and head of zebrafish. Especially, this probe could be applied in quantitative analysis of mercury ions in tap water, green tea, sea shrimp and soil. This work provided a practical tool for the detection of mercury ions in living systems and quantitative analysis in real samples.
作者机构：
[Yin, Jun] Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.;Cent China Normal Univ, Hubei Int Sci & Technol Cooperat Base Pesticide &, Wuhan 430079, Peoples R China.;Cent China Normal Univ, Int Joint Res Ctr Intelligent Biosensing Technol, Wuhan 430079, Peoples R China.;Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构：
[Yin, Jun] C;Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
关键词：
Alkali metal ions;Bioimaging application;Fluorescent dyes;Fluorescent probes;pH
摘要：
The homeostasis of acid/base and alkali metal played critical roles in life process. To get insight into their functional mechanism, a large amount of detectors, especially based on organic fluorescent probes have been largely developed and used to monitor the dynamic changes of pH and alkali metal ions. Importantly, fluorescent probes provide a portable means to carry out a real-time determination and even a clinical diagnosis for abnormal pathological states. Over the past decades, numerous fluorescent probes for the pH and alkali metals analytes have been extensively developed and applied in living systems. In this review, we outlined the recent advances on fluorescent probes for pH and alkali metal ions containing their sensing mechanism, binding modes and application. (C) 2020 Elsevier B.V. All rights reserved.
作者机构：
[Chen, Zhao; Liu, Sheng Hua; Wang, Xiao-Yan; Yin, Jun] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.;[Yin, Ya] South Cent Univ Nationalities, Coll Chem & Mat Sci, Hubei Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China.;[Chen, Zhao] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Jiangxi, Peoples R China.;[Liu, Sheng Hua] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China.
通讯机构：
[Wang, Xiao-Yan; Chen, Zhao; Liu, Sheng Hua] K;Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China.;Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China. and Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, PR China. chenzhao666@126.com;Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China. and State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China
作者机构：
[Liu, Shenghua; Yin, Jun; Han, Xie; Ma, Xiaoxie] Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensing Technol, Key Lab Pesticide & Chem Biol,Minist Educ,Hubei I, Wuhan 430079, Peoples R China.;[Chi, Weijie; Liu, Xiaogang; Wang, Chao] Singapore Univ Technol & Design, Singapore 487372, Singapore.;[Han, Xie] Wuhan Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430081, Peoples R China.
通讯机构：
[Xiaogang Liu] S;[Jun Yin] K;Singapore University of Technology and Design, Singapore 487372, Singapore<&wdkj&>Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, China
摘要：
Understanding the physical mechanisms governing aggregation-induced-emission (AIE) and aggregation-caused-quenching plays a vital role in developing functional AIE materials. In this work, tetraphenylethene (TPE, a classical AIEgen) and naphthalimide (NI, a popular fluorophore with ACQ characteristics) were connected through non-conjugated linkages and conjugated linkages. We showed that the nonconjugated-linkage of TPE to NI fragments leads to substantial PET in molecular aggregates and ACQ. In contrast, the conjugated connection between TPE and NI moieties results in the AIE phenomenon by suppressing twisted intramolecular charge transfer. This work provides an important guideline for the rational design of AIE materials.
通讯作者：
Zhaochao Xu<&wdkj&>Jun Yin<&wdkj&>Xiaogang Liu
作者机构：
[Chi, Weijie; Liu, Xiaogang; Wang, Chao; Wu, Xia] Singapore Univ Technol & Design, Fluorescence Res Grp, Singapore 487372, Singapore.;[Li, Dongyang; Yin, Jun; Han, Xie] Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensing Technol, Key Lab Pesticide & Chem Biol,Minist Educ,Hubei I, Wuhan 430079, Peoples R China.;[Wang, Chao; Xu, Zhaochao; Li, Jin] Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China.
通讯机构：
[Zhaochao Xu] C;[Jun Yin] K;[Xiaogang Liu] F;Fluorescence Research Group, Singapore University of Technology and Design, Singapore 487372, Singapore<&wdkj&>Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, China<&wdkj&>CAS Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
关键词：
Energy transfer;Electron transfer;Polarity probes;Environmental sensitivity
摘要：
Energy transfer and electron transfer are both fundamental mechanisms enabling numerous functional materials and applications. While most materials systems employ either energy transfer or electron transfer, the combined effect of energy and electron transfer processes in a single donor/acceptor system remains largely unexplored. Herein, we demonstrated the energy transfer followed by electron transfer (ETET) process in a molecular dyad TPE-NBD. Due to energy transfer, the fluorescence of TPE-NBD was greatly enhanced in non-polar solvents. In contrast, polar solvents activated subsequent electron transfer and markedly quenched the emission of TPE-NBD. Consequently, ETET endows TPE-NBD with significant polarity sensitivities. We expect that employing ETET could generate many functional materials with unprecedented properties, i.e., for single laser powered multicolor fluorescence imaging and sensing.
作者机构：
[Liu, Sheng Hua; Chen, Weijie; Yin, Jun; Chen, Huijuan] Cent China Normal Univ, Key Lab Pesticide & Chem Biol,Coll Chem, Minist Educ,Int Joint Res Ctr Intelligent Biosens, Hubei Int Sci & Technol Cooperat Base Pesticide &, Wuhan 430079, Peoples R China.;[Liu, Sheng Hua; Chen, Weijie; Yin, Jun; Chen, Huijuan] Hubei Univ, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China.;[Yin, Jun; Xie, Yuan] Guangdong Prov Key Lab Radioact & Rare Resource U, Shaoguan 512026, Peoples R China.;[Lin, Yan] Jiangxi Univ Tradit Chinese Med, Dept Pharm, Nanchang 330013, Jiangxi, Peoples R China.
通讯机构：
[Jun Yin] K;Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, China<&wdkj&>Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan 430062, China<&wdkj&>Guangdong Provincial Key Laboratory of Radioactive and Rare Resource Utilization, Shaoguan 512026, China
摘要：
The photoisomerization properties of azo derivatives have been widely used in the fields of materials and biology. One serious restriction to the development of functional azo-based materials is the necessity to trigger switching by UV light, which damage the corresponding surfaces and penetrate only partially through the matter. Therefore, developing the visible and near-infrared light activated azo switches can solve this problem. This review provides a summary of molecular design strategies for driving the isomerization of azo derivatives with visible light and near-infrared light: (1) smart design directly excited by visible light, (2) the addition of upconversion nanoparticles, (3) the employment of two-photon absorption, (4) indirect excitation in combination with metal sensitizer. (c) 2021 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
